Calibration of nebular emission-line diagnostics:
II. Abundances
M.S. Oey and J.C. Shields
We examine standard methods of measuring nebular chemical abundances,
including estimates based on direct T_e measurements, and also
emission-line diagnostics. We use observations of the LMC H II regions
DEM L199, DEM L243, DEM L301, and DEM L323, whose ionizing stars have
classifications ranging from O7 to WN3.
Following common practice, we assume a two-zone T_e
structure given by T(O^{++}) and T(O^+) to compute ionic
abundances. We compare with photoionization models tailored to the
observed properties of the individual objects, and emphasize
the importance of correctly relating T_e in the two zones, which can
otherwise cause errors of ~0.2 dex in abundance estimates. The
data show no spatial variations or local metallicity enhancements to
within 0.1 -- 0.15 dex in any of the objects, notably including DEM
L199, which hosts three WR stars.
Our data agree well with both the modeled R23 and S23 abundance
diagnostics for O and S. We present the first theoretical tracks for
S23, which are in excellent agreement with a larger available
dataset. However, contrary to earlier suggestions, S23 is
much more sensitive to the ionization parameter (U) than
is R23. This occurs because S23 does not sample [S IV],
which is often a significant population. We therefore introduce
S234=([S II]+[S III]+[S IV])/H-beta
and demonstrate that it is virtually independent of
U. Predicted and observed spatial variations in S234 are
thus dramatically decreased in contrast to S23. The intensity of
[S IV]10.5 microns can be easily estimated from the simple
correspondence between [S IV]/[S III] and [O III]/[O II]. Using this method
to estimate S234 for data in the literature yields excellent agreement
with our model tracks, hence we give a theoretical calibration for
S234. Our models show that the double-valued structure of
S23 and S234 remains an important problem as for
R23, and presently we consider
calibrations of these S diagnostics reliable only at Z ~<
0.5 Z_sol. However, the slightly larger dynamic range and excellent
compatibility with theoretical predictions suggest the S
parameters to be more effective abundance diagnostics than R23.
ApJ, 539, 687
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